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Oftentimes the rate of cooling occurs rapidly enough to prohibit the complete transformation of calcium-rich feldspar into sodium-rich feldspar.
In these instances, the feldspar crystals will have calcium-rich interiors surrounded by zones that are progressively richer in sodium.
Lava erupting earlier would come from the top of the magma chamber, and lava erupting later would come from lower down.
A number of processes could cause the parent substance to be depleted at the top of the magma chamber, or the daughter product to be enriched, both of which would cause the lava erupting earlier to appear very old according to radiometric dating, and lava erupting later to appear younger.
Here I want to concentrate on another source of error, namely, processes that take place within magma chambers.
Such processes can cause the daughter product to be enriched relative to the parent, which would make the rock look older, or cause the parent to be enriched relative to the daughter, which would make the rock look younger.
This calls the whole radiometric dating scheme into serious question.
The general idea is that many different minerals are formed, which differ from one another in composition, even though they come from the same magma.
The mineral makeup of an igneous rock is ultimately determined by the chemical composition of the magma from which it crystallized.
The following quote from The Earth: An Introduction to Physical Geology by Tarbuck & Lutgens, pp.